Yellow crystal, soluble in benzene, toluene, insoluble in ether and alcohol, sensitive to air, cold storage away from light. Tetri (triphenylphosphine) palladium, as an important transition metal catalyst, can be used to catalyze a variety of Chemicalbook reactions such as coupling, oxidation, reduction, elimination, rearrangement and isomerization. Its catalytic efficiency is very high, and it can catalyze many reactions that are difficult to occur under the action of similar catalysts. The reagent is obtained by the reduction of PdCl2(Ph3P)2 with hydrazine, or by the reaction of Pd2(DBA)3 with PPh3.
1.Special catalyst for the synthesis of medicine and pesticide (methamidoavermectin benzoate). Catalysts for transversely coupled reactions are widely used in important isomerization reactions.
2. Hydrosilylation, isomerization, carbonylation, oxidation, C-C bond formation and other reactions. For coupling reaction, Heck reaction, Sonogashira reaction, Stille reaction, Suzuki reaction.
3. Negishi coupling, Suzuki coupling, Stille coupling and Sonogashira coupling catalysts; Buchwald-Hartwig amination catalysts; vinyl iodide carbonylation catalysts; aryl bromide reduction catalysts; Carbon-Tin bonding catalysts.
Loaʻa iā mākou nā hale hana kiʻekiʻe me ka pilina hohonu, hiki iā ia ke hāʻawi iā ʻoe i nā huahana kiʻekiʻe a me nā kumukūʻai hoʻokūkū. A hiki iā mākou ke hāʻawi i nā uku no nā kūʻai nui. A ke hui pū nei mākou me nā ʻoihana lawe ukana ʻoihana he nui, hiki ke hāʻawi i nā huahana me ka palekana a me ka maʻalahi i kou mau lima. ʻO ka manawa hoʻouna ma kahi o 3-20 mau lā ma hope o ka hōʻoia ʻana o ka uku.
Tetrakis(triphenylphosphine)palladium(0) |
14221-01-3 | 120203 | Pd[P(C6H5)3]4 | 1155.58 | 20 |
'ikamu | In-house Standard | Nā hualoaʻa | |||
Apperance | Yellow to yellow-green crystalline powder | Hoʻokō | |||
Assay/Pd | ≥ 9.2% | Hoʻokō | |||
Lae hehee | 103-107ºC | Hoʻokō | |||
Solubility | Soluble in benzene, toluene, ethanol and chloroform. Insoluble in ethers. Air, light, hot and moisture sensitive. | Hoʻokō | |||
Purity | ≥ 99% | Hoʻokō |
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